Hi,
I got the same setup with you and try to find the way to activate so call Native DSD
But the issue is not come from player, it comes from the DAC.
Looking the text here
TEAC's new UD-501 is the star of the 501 series. The UD-501 supports Direct Stream Digital (DSD) playback at either 2.8 MHz or 5.6MHz (DXD) rates. PCM audio is supported up to 384kHz/32-bit resolution. It connects to your computer over USB using ASIO 2.1 or DoP.
You need ASIO 2.1 Driver where as Interface support is normally restricted to Microsoft Windows.
Further, I could not recognize Native DSD vs DoP playback with blind test.
So be happy with the Pi and Rune.