Unless you absolutely need to have the amp in the same enclosure with the RasPi, I don't see why you couldn't use any of the TPA3116D2-based amps. You get about 2x50W (rather optimistic, realistically it's more like 2x40W with 19V power supply).
However, it sure does get plenty loud
If you need an amp for throwing parties, then you'll need something more powerful, anyway (and rather expensive). However, there is still a cheap amp option - TDA7498 , which is 2x100W, and more powerful than the usual TPA3116 amps... It needs a bit more power, though (20V/5A as a minimum).
I've been using RaspI + Rune + TDA3116 amps for quite some time now, and I can honestly say that I haven't been able to find anything in that price range (and much more expensive) with equal sound quality.
For anything better (high-end audio territory) be prepared to pay at least 50 times more....
So, RasPi + Rune + cheap 24/192 DAC (Sabre ES9023 comes to mind) + external TPA3116D2 amp = hifi hi-res sound on a budget
Regards,
Denis